Are here any SCENTS that can wake up somebody up INSTANTLY?

Answer:
Ammonia, it is what is in smelling salt.

BUT it is dangerous and can assassinate.

Smelling salts.

Yes I'm sure near are!

Go to a drug store and buy a bottle of ammonia or some old fashioned smelling salt.

I don't know if this is "instantly" enough, but citrus scent particularly red and tangerine have a incredibly energizing effect.

As far as essential oils jump? Orange, Cinnamon Bark, Lemon, Tangerine